Chemical Thermodynamics and Kinetics

Course Description

This microlecture series from TMP Chem covers the content of an undergraduate course on chemical thermodynamics and kinetics. Topics include gas equations of state, statistical mechanics, the laws of thermodynamics, enthalpy, entropy, Gibbs and Helmholtz energies, phase diagrams, solutions, equilibrium, electrochemistry, kinetic theory of gases, reaction rates, and reaction mechanisms.

Chemical Thermodynamics and Kinetics
A screenshot from the Thermodynamics Review lecture. This course provides well-organized clear microlectures on various thermochemistry topics, including the first, second and third laws of thermodynamics.
Not yet rated

Video Lectures & Study Materials

# Lecture Play Lecture
I. THERMODYNAMICS: Gas Properties
1 Introduction (5:39) Play Video
2 Ideal Gas Equation (11:14) Play Video
3 van der Waals Gas Equation (7:57) Play Video
4 Gas Equation Example (12:19) Play Video
5 Virial Equation of State (8:24) Play Video
6 Molecular Interaction Functions (10:08) Play Video
7 Critical Point (11:41) Play Video
8 Reduced Properties (13:45) Play Video
9 Gas Properties Review (4:24) Play Video
II. Introduction to Statistical Mechanics
10 Energy Quantization (10:11) Play Video
11 Boltzmann Factor (8:30) Play Video
12 Average Ensemble Energy (9:21) Play Video
13 Partition Function Example 1 (9:53) Play Video
14 Partition Function Example 2 (6:51) Play Video
15 Partition Function Example 3 (7:02) Play Video
16 Molecular Partition Function 1 (7:43) Play Video
17 Molecular Partition Function 2 (8:20) Play Video
18 Translational Partition Function (12:20) Play Video
19 Rotational Partition Function (11:02) Play Video
20 Statistical Mechanics Review (4:26) Play Video
III. First Law of Thermodynamics: Enthalpy
21 First Law (8:52) Play Video
22 Pressure-Volume Work (8:30) Play Video
23 State and Path Functions (8:04) Play Video
24 Reversible Processes (9:19) Play Video
25 Isothermal Processes (4:49) Play Video
26 Adiabatic Processes (8:58) Play Video
27 Adiabatic / Isothermal Comparison (6:49) Play Video
28 Microscopic Heat and Work (6:31) Play Video
29 Enthalpy (5:59) Play Video
30 Enthalpy Example (14:05) Play Video
31 Heat Capacity (8:12) Play Video
32 Transition Enthalpy (9:37) Play Video
33 Reaction Enthalpy (5:14) Play Video
34 Hess's Law (4:47) Play Video
35 Formation Enthalpy (4:29) Play Video
36 Hrxn from Hformation (7:23) Play Video
37 Hrxn Temp Dependence (4:43) Play Video
38 First Law / Enthalpy Review (7:41) Play Video
IV. Second Law of Thermodynamics: Entropy
39 Spontaneous Processes (5:36) Play Video
40 Entropy (8:34) Play Video
41 Expansion Entropy (6:21) Play Video
42 Second Law (5:14) Play Video
43 Entropy Example (9:53) Play Video
44 Statistical Entropy (7:39) Play Video
45 Gibbs Entropy (8:28) Play Video
46 Reversible Entropy (5:15) Play Video
47 Heat Engines (8:30) Play Video
48 Second Law / Entropy Review (5:08) Play Video
V. Third Law of Thermodynamics: Absolute Entropy
49 Entropy Temp Dependence 1 (9:21) Play Video
50 Entropy Temp Dependence 2 (8:20) Play Video
51 Third Law (5:36) Play Video
52 Transition Entropy (7:09) Play Video
53 Debye T^3 Law (6:42) Play Video
54 Absolute Calorimetric Entropy (11:36) Play Video
55 Absolute Statistical Entropy (11:17) Play Video
56 Residual Entropy (8:04) Play Video
57 Reaction Entropy (6:39) Play Video
58 Third Law / Absolute Entropy Review (5:19) Play Video
VI. Gibbs and Helmholtz Free Energies
59 Helmholtz Energy (8:34) Play Video
60 Gibbs Energy (10:40) Play Video
61 Natural Variables (11:15) Play Video
62 Maxwell Relations: Concept (7:45) Play Video
63 Maxwell Relations: Summary (3:53) Play Video
64 Maxwell Relations: Example (4:59) Play Video
65 Standard Entropy Correction (14:05) Play Video
66 Gibbs-Helmholtz Equation (8:50) Play Video
67 Fugacity (10:55) Play Video
68 Fugacity Coefficient (12:04) Play Video
69 Gibbs / Helmholtz Energy Review (7:40) Play Video
VII. Phase Diagrams
70 Phase Diagrams (8:49) Play Video
71 Gibbs Energy of Phases (10:16) Play Video
72 Chemical Potential (7:18) Play Video
73 Clapeyron Equation (10:02) Play Video
74 Clausius-Clapeyron Equation (10:06) Play Video
75 Statistical Chemical Potential (9:05) Play Video
76 Phase Diagrams Review (6:13) Play Video
VIII. Liquid-Liquid Solutions
77 Partial Molar Quantities (7:36) Play Video
78 Gibbs-Duhem Equation (12:44) Play Video
79 Solution Chemical Potential (13:16) Play Video
80 Raoult's Law (11:16) Play Video
81 Pressure-Composition Diagram (12:49) Play Video
82 Temperature-Composition Diagram (7:54) Play Video
83 Energy of Mixing (10:47) Play Video
84 Henry's Law (9:27) Play Video
85 Activity (9:28) Play Video
86 Standard Activity (9:31) Play Video
87 Liquid-Liquid Solutions Review (8:22) Play Video
IX. Solid-Liquid Solutions
88 Molality and Molarity (9:07) Play Video
89 Non-Volatile Solutes (17:22) Play Video
90 Colligative Properties (4:52) Play Video
91 Freezing Point Depression (16:51) Play Video
92 Osmotic Pressure (10:15) Play Video
93 Electrolyte Activity (12:57) Play Video
94 Debye-Huckel Law (9:44) Play Video
95 Solid-Liquid Solutions Review (9:02) Play Video
X. Chemical Equilibrium
96 Extent of Reaction (10:42) Play Video
97 Equilibrium Constant Derivation (10:40) Play Video
98 Le Chatalier's Principle (11:00) Play Video
99 Concentration Equilibrium Constant (7:27) Play Video
100 Standard Reaction Gibbs Energy (9:59) Play Video
101 Equilibrium Gibbs Energy (17:11) Play Video
102 Reaction Quotient (5:24) Play Video
103 Reaction Spontaneity (6:43) Play Video
104 Van't Hoff Equation (11:41) Play Video
105 Fugacity Equilibrium Constant (5:49) Play Video
106 Activity Equilibrium Constant (8:17) Play Video
107 Condensed Phase Activity (10:09) Play Video
108 Equilibrium Review (8:18) Play Video
XI. Electrochemistry
109 Electrochemical Cells (10:55) Play Video
110 Half Cell Reactions (8:13) Play Video
111 Cell Diagrams (8:28) Play Video
112 Electromotive Force (7:47) Play Video
113 Nernst Equation (10:40) Play Video
114 Standard Reduction Potential (10:26) Play Video
115 Electrochemistry Example (16:28) Play Video
116 Electrochemical Enthalpy and Entropy (6:09) Play Video
117 Ionic Gibbs Energy (7:09) Play Video
118 Solubility Product (8:45) Play Video
119 Batteries (7:48) Play Video
120 Electrochemistry Review (6:44) Play Video
121 Summary of Thermodynamics Chapters (15:11) Play Video
XII. KINETICS: Kinetic Theory of Gases
122 Introduction (4:43) Play Video
123 Average Kinetic Energy (14:46) Play Video
124 Average Velocity (9:50) Play Video
125 Maxwell-Boltzmann Distribution (12:57) Play Video
126 Mean Free Path (12:14) Play Video
127 Total Collision Rate (8:01) Play Video
128 Kinetic Theory of Gases Review (6:55) Play Video
XIII. Reaction Rates
129 Reaction Rates (8:38) Play Video
130 Rate Laws (8:15) Play Video
131 First Order Reactions (7:28) Play Video
132 Second Order Reactions (5:51) Play Video
133 Half Life (9:52) Play Video
134 Determining Rate Laws (8:49) Play Video
135 Reversible Reactions (10:21) Play Video
136 Activation Energy (8:22) Play Video
137 Reaction Coordinate (9:48) Play Video
138 Reaction Rates Review (6:19) Play Video
XIV. Reaction Mechanisms
139 Reaction Mechanisms (8:01) Play Video
140 Detailed Balance (6:56) Play Video
141 Rate Determining Step (9:40) Play Video
142 Steady-State Approximation (10:21) Play Video
143 Unimolecular Reactions (12:34) Play Video
144 Catalysis (8:33) Play Video
145 Michaelis-Menton Mechanism (13:46) Play Video
146 Reaction Mechanisms Review (6:56) Play Video
147 Summary of Kinetics Chapters (7:41) Play Video

Comments

There are no comments. Be the first to post one.
  Post comment as a guest user.
Click to login or register:
Your name:
Your email:
(will not appear)
Your comment:
(max. 1000 characters)
Are you human? (Sorry)
 
Disclaimer:
CosmoLearning is promoting these materials solely for nonprofit educational purposes, and to recognize contributions made by TMP Chem (TMP Chem) to online education. We do not host or upload any copyrighted materials, including videos hosted on video websites like YouTube*, unless with explicit permission from the author(s). All intellectual property rights are reserved to TMP Chem and involved parties. CosmoLearning is not endorsed by TMP Chem, and we are not affiliated with them, unless otherwise specified. Any questions, claims or concerns regarding this content should be directed to their creator(s).

*If any embedded videos constitute copyright infringement, we strictly recommend contacting the website hosts directly to have such videos taken down. In such an event, these videos will no longer be playable on CosmoLearning or other websites.