Final Exam Review 
Final Exam Review
by UC Irvine / Rachel Martin
Video Lecture 26 of 26
Copyright Information: Martin, Rachel. Molecular Structure & Statistical Mechanics 131B (UCI OpenCourseWare: University of California, Irvine), [Accessed January 23, 2015]. License: Creative Commons Attribution-ShareAlike 3.0 United States License. (
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Date Added: January 23, 2015

Lecture Description

Recorded on March 16, 2013. Slides: 04:08- Final Exam Review 04:15- The Canonical Ensemble 05:17- The Canonical Ensemble, Slide 2 08:40- Point Groups: Flow Chart 09:34- Example: OCl2 11:27- Group Theory- Molecular Motion 13:08- Group Theory- Molecular Motion, Slide 2 15:03- Group Theory- Molecular Motion, Slide 3 16:05- Big Picture: Spectroscopy 17:13- Raman Spectroscopy 17:48- Vibration and Rotational Energy Levels 18:37- IR Spectrum of HCl 18:56- Bond Length of HCl 19:43- Vibrational Spectroscopy: Use the Spectrum to Estimate the Force Constant 20:51- Vibrational Spectroscopy: Why is There No Peak in the Center of These Spectra? 22:32- Vibrational Spectroscopy: Summary of Example 23:52- Degeneracy 24:52- Vibrational Raman Spectroscopy 24:58- Term Symbols for Atoms 25:57- Hund's Rule 26:33- Term Symbols for Linear Molecules 30:48- Selection Rules 33:41- Electronic Spectroscopy 34:54- Nuclear Zeeman Effect 26:30- Spin Quantum Number 37:06- Zeeman Basis 38:48- Raising and Lowering Operators 40:17- Eigenstates and Eigenvalues 40:35- ^(1)H NMR Spectroscopy is a Powerful tool for Structure Elucidation 41:54- J-Coupling: Product Basis 42:15- NMR Spectra 42:59- Statistical Mechanics 43:48- Relative Populations 44:13- Molecular Partition Function 45:00- 2-Level System Partition Function

Course Index

Course Description

Principles of quantum mechanics with application to the elements of atomic structure and energy levels, diatomic molecular spectroscopy and structure determination, and chemical bonding in simple molecules. Chemistry Dept. | Physical Sciences Sch. | University of California, Irvine


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