Recorded on May 29, 2012

Index of Topics:

3:12-Carbohydrates
8:39-Lactose
12:47-Subunits of Lactose
15:38-Alpha-D-Glucose
18:04-Anomers
21:51-Interconversion of Glucose Anomers
25:29-Interconverting Lactose?
28:26-Forms of Galactose
32:15-Optical Rotation
37:25-Chair Representation of Glucose
39:11-Haworth Representation of Glucose
42:40-Open Form Representation of Glucose
46:56-Fischer Projection
51:15-Converting Haworth Projection to a Fischer Projection
53:48-PyMOL Demonstration
1:02:49-Using Fischer Projections to Make Different Sugar Molecules
1:04:32-8 D Sugars

1. Introduction to Carboxylic Acids.
2. Reactivity of Carbonyl Compounds.
3. Reactions of Organometallic Reagents.
4. Reactions and Protecting Groups.
5. Aldehydes and Ketones: Reactions.
6. Formation of Imines & Enamines from Aldehydes & Ketones.
7. Acid-Catalyzed Formation of Hydrates, Hemiacetals, & Acetals.
8. The Chemistry of the Carboxylic Acid Family.
9. Reactions of Carboxylic Acids, Esters, Amides, & Nitriles.
10. Enols and Enolates.
11. More Reactions of Enols and Enolates.
12. The Aldol Reaction and the Michael Reaction.
13. The Robinson Annulation and the Claisen Reaction.
14. Introduction to Amines: Properties and Synthesis.
15. Hofmann Degradation, Diazotization, & Aryl Diazonium Salts.
16. Introduction to Carbohydrates: Structure and Stereochemistry
17. More Structure, Stereochemistry, & Reactions of Carbohydrates.
18. Amino Acids, Peptides, and Proteins.
19. Organometallic Reactions in Organic Synthesis.

This is the third quarter course in the organic chemistry series. Topics covered include: Fundamental concepts relating to carbon compounds with emphasis on structural theory and the nature of chemical bonding, stereochemistry, reaction mechanisms, and spectroscopic, physical, and chemical properties of the principal classes of carbon compounds.

Organic Chemistry 51C is part of OpenChem. http://ocw.uci.edu/collections/open_chem