
Lecture Description
Phenol Synthesis
Hydroxylations of Haloarenes, Williamson synthesis, phenols and esters, electrophilic aromatic substitution, Kolbe-Schmitt reaction, Allylxyphenols and the Claisen rearrangement, Cope rearrangement, Benzenediols-Benzoquinones, Arenamines, Retrosynthetic connection of phenols to Arenes
Course Index
- Lecture 1: Delocalized Pi Systems: 2-Propenyl
- Lecture 2: Delocalized Pi Systems: Butadiene, Extended Conjugation, and the Diels-Alder Cycloaddition
- Lecture 3: Electrocyclic Reactions
- Lecture 4: Benzene and Aromaticity, Huyckel Rule
- Lecture 5: Electrophilic Aromatic Substitution, Activators and Deactivators
- Lecture 6: Directing Effects in Electrophilic Aromatic Substitution and Synthetic Applications
- Lecture 7: Electrophilic Aromatic Substitution of Naphthalene; Aldehydes and Ketones: Names and Old Chemistry
- Lecture 8: Aldehydes and Ketones: Reversible Addition Reactions
- Lecture 10: Wolff-Kishner Reduction, Wittig Reaction, Baeyer-Villiger Oxidation, Enols, Enolates, Enals, Enones
- Lecture 11: Aldehydes & Ketones: Kinectic Energy, Halogenation, Alkylation, Enamines, Aldol condensation, Carbonyls
- Lecture 12: Unsaturated Carbonyls, HCN, O & N Nucleophiles, Ether formation, Organometallics, Carboxylic Acids
- Lecture 13: Graphene, Acidity, Basicity, Hydrolysis, Reactions, Nucleophilic substitution, Synthesis, Anhydrides, Esters
- Lecture 14: Ester, Lactones, Amides, Penicillins, lactams, Hell-Volhard-Zelinsky Reaction, Reactivity, Alcohols, Amines
- Lecture 15: Organometallics, acyl chlorides and aldehydes, Friedel-Crafts, Grignard and Hydride reagents
- Lecture 16: Amide enolates and amidates, Hofmann rearrangement, Alkanenitriles, Alkaloids, Nylon
- Lecture 17: Ammonium Salts
- Lecture 18: Chemistry of Substituted Benzenes
- Lecture 20: Phenol Synthesis
- Lecture 21: Ester Enolates, Mixed Ketone and the Claisen Condensation, Michael Addition, Robinson Annulation
- Lecture 22: Stoichiometric reagents, alkanal coupling using thiazolium ion catalyst, aldehyde coupling, Carbohydrates
- Lecture 23: Formation of Glucose and Fructose, Glucopyranoses, Reactions of Sugars, Esters and Ethers: Protection
- Lecture 24: Higher Saccharides: Sucrose, Lactose, Cellulose, Starch, Glycogen. Heterocycles
- Lecture 25: Aromatic Heterocycles, Pyridine: Azabenzene, Amino Acids
- Lecture 26: Synthesis of Amino Acids, Peptides, Protein, Edman degradation
- Lecture 27: Synthesis of Polypeptides, Nucleic Acids, Protein Synthesis, Genetechnology, Human Genome
Course Description
Chemistry 3B, 002: Chemical Structure and Reactivity (Fall 2010)
In this course, Prof. K. Peter Vollhardt gives 25 video lectures on chemical structure and reactivity.
Topics: Conjugation, aromatic chemistry, carbonyl compounds, carbohydrates, amines, carboxylic acids, amino acids, peptides, proteins, and nucleic acid chemistry. Ultraviolet spectroscopy and mass spectrometry will be introduced.
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