Metastable Anions & Virtual Orbitals 
Metastable Anions & Virtual Orbitals
by U of U / Jack Simons
Video Lecture 9 of 12
Not yet rated
Views: 641
Date Added: February 3, 2015

Lecture Description

Special tricks for studying metastable anions; variational collapse; virtual orbitals are difficult to identify- examples; long-range potentials and the centrifugal potential; valence and long-range components of the wave function; relation to electron scattering; charge stabilization method; the stabilization method.

Course Index

Course Description

These lectures are intended to provide graduate students in chemistry and related fields, experimental chemists, and theoretical chemists specializing in other sub-disciplines with an introduction to the underpinnings of electronic structure theory. I have tried to present the material with a focus on physical and conceptual content while keeping the mathematical level appropriate to the broad audience just described. For those who want access to additional information at or a bit beyond the level of these lectures, I can recommend the following texts:

T. Helgaker, J. Olsen, and P. Jorgensen, Molecular Electronic Structure Theory, Wiley (2000). I think this is the best book to use as a source for further details about the methods introduced in these lectures.

J. Simons, and J. Nichols, Quantum Mechanics in Chemistry, Oxford University Press (1997);
J. Simons, An Introduction to Theoretical Chemistry, Cambridge University Press (2003). These two books are good at explaining the concepts underlying the equations, offer good physical pictures of what the theories contain, and make connections to experiments.

J. Simons, Energetic Principles of Chemical Reactions, Jones and Bartlett Publishers, Inc. (1983). This is a good source for making connections between electronic structure theory and reaction dynamics.

Other good sources are the web site, as well as that of the theoretical chemistry Summer School where lectures on electronic structure theory, dynamics, and statistical mechanics appear.
I hope you enjoy and benefit from these lectures and I wish you the very best in your own scholarly career.

- Dr. Simons (from official website:


There are no comments. Be the first to post one.
  Post comment as a guest user.
Click to login or register:
Your name:
Your email:
(will not appear)
Your comment:
(max. 1000 characters)
Are you human? (Sorry)