Quantum Chemistry and Spectroscopy
Video Lectures
Displaying all 159 video lectures.
I. Early Quantum Theory | |
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Lecture 1![]() Play Video |
Introduction Short physical chemistry introducing quantum chemistry. Quantum chemistry is quantum mechanics applied to chemical systems such as electrons and nuclei. Quantum mechanics describes the behavior of very small microscopic objects, which behave differently than large macroscopic objects. --- All TMP Chem content is 100% free and ad-free for everyone, everywhere. All content is produced by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/QqkIPhf.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=_r5TtnjRzaY&index=2&list=PLm... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Thermo Intro: https://www.youtube.com/watch?v=A0dIrKGN7Vg&index=1&list=PLm... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Quantum Chemistry And Spectroscopy Chapters --- Early Quantum Theory: https://www.youtube.com/playlist?list=PLm8ZSArAXicLxU2lg3Nvn... Classical Waves: https://www.youtube.com/playlist?list=PLm8ZSArAXicIoSE0BFPgL... Particle in a Box / Schrodinger Equation: https://www.youtube.com/playlist?list=PLm8ZSArAXicL6ArmHxHxg... Fundamentals of Quantum Mechanics: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Harmonic Oscillator: https://www.youtube.com/playlist?list=PLm8ZSArAXicL4kdvchwcg... Rigid Rotor: https://www.youtube.com/playlist?list=PLm8ZSArAXicIlRL7FdtY3... Hydrogen Atom: https://www.youtube.com/playlist?list=PLm8ZSArAXicLqbzYEN863... Many-Electron Atoms: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Diatomic Molecules: https://www.youtube.com/playlist?list=PLm8ZSArAXicLZWxTcr_XW... Polyatomic Bonding: https://www.youtube.com/playlist?list=PLm8ZSArAXicImNhMOwgaS... Symmetry and Group Theory: https://www.youtube.com/playlist?list=PLm8ZSArAXicKX9g2IA7FA... Nuclear Magnetic Resonance: https://www.youtube.com/playlist?list=PLm8ZSArAXicIJ7cXhWv53... Particle in a Ring: https://www.youtube.com/playlist?list=PLm8ZSArAXicKr7sfnShlh... --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 2![]() Play Video |
Blackbody Radiation Short physical chemistry lecture on blackbody radiation. When a blackbody is heated it emits radiation of varying intensity versus frequency. Classical theory makes an incorrect prediction of the spectrum, which is fixed by Planck's quantum hypothesis. --- All TMP Chem content and 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/7N2KRUt.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=7i6toEAZiV0&index=3&list=PLm... Previous Video / Course Intro : https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLxU2lg3Nvn... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 3![]() Play Video |
Photoelectric Effect Short physical chemistry lecture on the photoelectric effect. When ultraviolet light hits a metal surface, electrons are ejected. Classical mechanics fails to predict the kinetic energy of these electrons, but Einstein's quantum hypothesis with light particles, photons, correctly predicts the experimental result. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker with no external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/fFq9dO9.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=DLmnh74MfSA&index=4&list=PLm... Previous Video: https://www.youtube.com/watch?v=_r5TtnjRzaY&index=2&list=PLm... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLxU2lg3Nvn... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 4![]() Play Video |
Rydberg Formula Short physical chemistry lecture on the Rydberg formula. When hydrogen atoms are heated, photons are emitted with distinct sets of wavelengths. These wavelengths are predicted using the Rydberg formula, which involves the use of two integer quantum numbers. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker, with no external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://i.imgur.com/fFq9dO9.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=A6YZ32W7_Ms&index=5&list=PLm... Previous Video: https://www.youtube.com/watch?v=7i6toEAZiV0&index=3&list=PLm... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLxU2lg3Nvn... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 5![]() Play Video |
Bohr Hydrogen Model 1: Radius Short physical chemistry lecture on the Bohr hydrogen model radius. Bohr assumed that in the hydrogen atom the electron travels in fixed circular orbits around the proton with quantized angular momentum. This leads to the expression for the Bohr radius, and quantized radii of orbit. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker with no external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://i.imgur.com/g6FNwMf.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=rkKhMRD_Lio&index=6&list=PLm... Previous Video: https://www.youtube.com/watch?v=DLmnh74MfSA&index=4&list=PLm... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLxU2lg3Nvn... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 6![]() Play Video |
Bohr Hydrogen Model 2: Energy Short physical chemistry lecture on the Bohr hydrogen model energy. Bohr assumed that the electron in the hydrogen atom travels in fixed circular orbits around the proton. This leads to an expression for the allowed energy levels of the atom which predict the Rydberg constant and Rydberg formula. --- All TMP Chem videos are 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker with no external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://i.imgur.com/PYyyMH8.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=T6PYbgVEHT4&index=7&list=PLm... Previous Video: https://www.youtube.com/watch?v=A6YZ32W7_Ms&index=5&list=PLm... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLxU2lg3Nvn... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 7![]() Play Video |
Wave-Particle Duality Short physical chemistry lecture on wave-particle duality. de Broglie proposed that matter, like light, has both wave and particle like properties. He described an equation for the wavelength of matter, which correctly predicts the Bohr quantization condition. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker with no external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Link to Graph: https://www.desmos.com/calculator/gazhf6fafx Notes Slide: http://i.imgur.com/4BFUd2G.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=cZbVl14wNkk&index=8&list=PLm... Previous Video: https://www.youtube.com/watch?v=rkKhMRD_Lio&index=6&list=PLm... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 8![]() Play Video |
Heisenberg Uncertainty Principle in Measurement Short physical chemistry lecture on the Heisenberg uncertainty principle in measurement. The Heisenberg uncertainty principle relates the uncertainty in position and momentum of a particle by providing a minimum value for their product. This video introduces the concept qualitatively through measurement. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker with no external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://i.imgur.com/rhxu2sc.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=OpTAXlTVnT4&index=9&list=PLm... Previous Video: https://www.youtube.com/watch?v=T6PYbgVEHT4&index=7&list=PLm... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLxU2lg3Nvn... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
II. Classical Waves | |
Lecture 9![]() Play Video |
Classical Wave Equation Short physical chemistry lecture on the classical wave equation. The classical wave equation describes the relationship between variations in wave displacement over space to the variation over time. We can separate this equation into a function of position and a function of time, both of which are sines and cosines. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes slide: http://i.imgur.com/IuaVSKs.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=wtcdLjAyEBM&index=10&list=PL... Previous Video: https://www.youtube.com/watch?v=cZbVl14wNkk&index=8&list=PLm... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIoSE0BFPgL... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 10![]() Play Video |
Vibrating String Short physical chemistry lecture on on the 1-dimensional vibrating string. Applying the classical wave equation to the case of a 1-dimensional vibrating string leads to a set of normal modes whose phases and amplitudes can be combined to produce a general solution of any function which obeys the boundary conditions. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://i.imgur.com/hYiMmXX.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=yNJ06JQDGEM&index=11&list=PL... Previous Video: https://www.youtube.com/watch?v=OpTAXlTVnT4&index=9&list=PLm... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIoSE0BFPgL... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 11![]() Play Video |
Vibrating String Animation Short physical chemistry lecture showing an animation of the 1-dimensional vibrating string solutions. The classical wave equation applied to a 1-dimensional vibrating string gives rise to a general solution which is a linear combination of stationary states. This animation shows the effect of varying the length, velocity, and coefficients of the wave. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Link to Graph: https://www.desmos.com/calculator/qlvo6pfd31 --- Video Links --- Next Video: https://www.youtube.com/watch?v=CSCSGFbt_Y0&index=12&list=PL... Previous Video: https://www.youtube.com/watch?v=wtcdLjAyEBM&index=10&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIoSE0BFPgL... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
III. Schrodinger Equation & Particle in a Box | |
Lecture 12![]() Play Video |
Schrodinger Equation "Derivation" Short physical chemistry lecture on "deriving" the Schrodinger equation. The Schrodinger equation defines the wavefunctions and energies of a quantum system for a given choice of potential energy function. It is typically taken to be a postulate, but using the classical wave equation and the de Broglie hypothesis we can "derive" it as the wave equation for quantum particles. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://i.imgur.com/pZgzikZ.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=ktrJ-sqaaBs&index=13&list=PL... Previous Video: https://www.youtube.com/watch?v=yNJ06JQDGEM&index=11&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL6ArmHxHxg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 13![]() Play Video |
Operators Short physical chemistry lecture on operators. An operator is something that acts on an object to create a new object. Observable properties in classical mechanics are represented in quantum mechanics by linear operators which act on wavefunctions. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker with no external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://i.imgur.com/H5RbK9I.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=cUUFIk0ISuY&index=14&list=PL... Previous Video: https://www.youtube.com/watch?v=CSCSGFbt_Y0&index=12&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL6ArmHxHxg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 14![]() Play Video |
Eigenvalues and Eigenfunctions Short physical chemistry lecture on eigenvalues and eigenfunctions. When an operator acts on a function and the result is a constant times that function, the function is an eigenfunction of that operator, and the constant is the eigenvalue for that eigenfunction. The Schrodinger equation is an eigenvalue equation for the Hamiltonian operator, the wavefunction, and the total energy. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://i.imgur.com/4AWkJJm.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=9TfQUie_OTM&index=15&list=PL... Previous Video: https://www.youtube.com/watch?v=ktrJ-sqaaBs&index=13&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL6ArmHxHxg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 15![]() Play Video |
Interpreting the Wavefunction Short physical chemistry lecture on interpreting the wavefunction. According to the Born interpretation of quantum mechanics the wavefunction times its complex conjugate is a probability density function for the particle. This means that the wavefunction must be normalized, or the integral of psi_star psi over all space must be 1. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliation. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://i.imgur.com/hqmBVc2.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=uK60QAKooyM&index=16&list=PL... Previous Video: https://www.youtube.com/watch?v=cUUFIk0ISuY&index=14&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL6ArmHxHxg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/watch?v=m4bM4djNnwQ&index=1&list=PLm... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 16![]() Play Video |
Particle in a Box Short physical chemistry lecture on the particle in a box model system. The particle in a box is a model for the translational motion of atoms and molecules. The potential is zero inside and infinite outside the box. Here we use the Schrodinger equation to solve for the wavefunctions and energy levels of the particle in a box in terms of the mass of the particle, length of the box, and the quantum number n. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://i.imgur.com/ARoaMTQ.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=EK6C6mpxP-g&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=9TfQUie_OTM&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL6ArmHxHxg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 17![]() Play Video |
Normalization Short physical chemistry lecture on normalizing the wavefunction. To find the value of the constant in front of the particle in a box wavefunctions, we must use the Born interpretation of the wavefunction, that the wavefunction squared is a probability density function. Setting the integral over all space of psi_star psi equal to 1 gives a value for this normalization constant. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://i.imgur.com/PPDPI0T.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=3p9jHJYCjII&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=uK60QAKooyM&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL6ArmHxHxg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 18![]() Play Video |
Particle in a Box Wavefunction Plots Short physical chemistry lecture showing plots of the particle in a box wavefunctions. The particle in a box wavefunctions are sine waves that increase by a half wave for every quantum number n. The wavefunctions and energies also depend on the length of the box l, mass of the particle m, and Planck's constant h. This animation shows the effect as we change each of these values. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Link to graph: https://www.desmos.com/calculator/h7tk8qyexz --- Video Links --- Next Video: https://www.youtube.com/watch?v=WRYSVj-FD48&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=EK6C6mpxP-g&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL6ArmHxHxg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 19![]() Play Video |
UV-Vis Spectra of Polyenes Short physical chemistry lecture on the uv-vis spectra of conjugated polyenes. The particle in a box model can be applied to the pi electrons of conjugated polyenes. Using bond lenths for l we can find the energy of pi to pi_star transitions for a conjugated polyene of given length, and see that those values compare favorably to the uv-vis spectral peaks from experiment. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/3eVmqm8.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=sCeUFzxowuQ&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=3p9jHJYCjII&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL6ArmHxHxg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 20![]() Play Video |
Average Position Short physical chemistry lecture on the average position of the particle in a box wavefunctions. The wavefunction contains all information needed to calculate all properties of a quantum system. Using the position operator and the expectation value formula, we can calculate the average value of position, position squared, and the uncertainty in position for the particle in a box wavefunctions. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/VkkGMR3.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=l4x6gkMxKEA&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=WRYSVj-FD48&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL6ArmHxHxg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 21![]() Play Video |
Average Momentum Short physical chemistry lecture on the average momentum of the particle in a box wavefunctions. Using the momentum operator and the expectation value formula we can compute the average momentum, momentum squared, and uncertainty in momentum of the particle in a box wavefunctions. Multiplying the uncertainties of momentum and position allows us to show that these wavefunctions obey the Heisenberg uncertainty principle. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://i.imgur.com/QDjFq3U.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=aXiyOUxUJAA&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=sCeUFzxowuQ&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL6ArmHxHxg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/watch?v=m4bM4djNnwQ&index=1&list=PLm... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 22![]() Play Video |
3-D Particle in a Box Short physical chemistry lecture on the 3-dimensional particle in a box. When we extend the particle in a box model to 3 dimensions we solve the Schrodinger equation by separation of variables. We get a product of 3 1-dimensional wavefunctions, each with their own energy and quantum number. The wavefunction is a product, and the energy a sum of these 1-dimensional components. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/dabtQFr.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=vtlgDgHLpfQ&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=l4x6gkMxKEA&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL6ArmHxHxg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 23![]() Play Video |
Degeneracy Short physical chemistry lecture on degeneracy in the 3-d particle in a box. Degeneracy occurs when multiple quantum states have the same energy. In the 3-dimensional particle in a box degeneracy occurs when the length of the box in various dimensions equals a multiple of one another. In general, symmetry leads to degeneracy. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/NxiZo5P.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=ppvk2hSYcG4&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=aXiyOUxUJAA&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL6ArmHxHxg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
IV. Fundamentals of Quantum Mechanics | |
Lecture 24![]() Play Video |
Postulates of Quantum Mechanics 1: Wavefunction Short physical chemistry lecture on the 1st postulate of quantum mechanics. Postulate 1 of quantum mechanics says that the state of the system is completely specified by the wavefunction, and the wavefunction times its complex conjugate is the probability density function of the particle. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://i.imgur.com/jISFuor.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=Kk1Gf-T2a-M&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=vtlgDgHLpfQ&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 25![]() Play Video |
Postulates of Quantum Mechanics 2: Operators Short physical chemistry lecture on the 2nd postulate of quantum mechanics. The second postulate of quantum mechanics states that for every observable property in classical mechanics there is a corresponding linear, Hermitian operator in quantum mechanics. --- All TMP Chem videos are 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/VSBrVGb --- Video Links --- Next Video: https://www.youtube.com/watch?v=hLgEO4WlfzU&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=ppvk2hSYcG4&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 26![]() Play Video |
Postulates of Quantum Mechanics 3: Measurement Short physical chemistry lecture on the 3rd postulate of quantum mechanics. Postulate 3 of quantum mechanics states that any measurement of a property must yield an eigenvalue of the operator for that property. --- All TMP Chem videos are 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://i.imgur.com/FWa9F4t.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=0H7xbGGBMGc&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=Kk1Gf-T2a-M&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 27![]() Play Video |
Postulates of Quantum Mechanics 4: Expectation Values Short physical chemistry lecture on the 4th postulate of quantum mechanics. Postulate 4 of quantum mechanics states that the average value of a property is determined by the expectation value formula for that operator. This leads to the result that there is zero uncertainty for a property if the wavefunction is an eigenfunction of the operator for that property. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/PNoA2qf.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=XjIBIc-Ldok&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=hLgEO4WlfzU&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/watch?v=m4bM4djNnwQ&index=1&list=PLm... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 28![]() Play Video |
Postulates of Quantum Mechanics 5: Schrodinger Equation Short physical chemistry lecture on the 5th postulate of quantum mechanics. Postulate 5 of quantum mechanics states that the wavefunction evolves in time according to the time-dependent Schrodinger equation. Separation of variables can be used to split the wavefunction into a spatial part multiplied by a complex exponential in time. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/4Yf9po7.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=aG_L3gym0uU&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=0H7xbGGBMGc&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 29![]() Play Video |
Commutators Short physical chemistry lecture on commutators of operators. The commutator of operators A and B is the operator that results from the difference of acting with B then A and acting with A then B. If the commutator of two operators is zero, then the operators commute. If operators don't commute, an uncertainty relationship exists between them. This leads to the Heisenberg uncertainty principle for position and momentum. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/0fKXddU.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=0Q_KmTOy07E&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=XjIBIc-Ldok&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 30![]() Play Video |
Hermitian Operators Short physical chemistry lecture on Hermitian operators. All measured values of physical properties in quantum mechanics must be eigenvalues of a linear operator. Physical properties must be real numbers. Operators in quantum mechanics must be Hermitian, because Hermitian operators are guaranteed to provide real numbers for their eigenvalues. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/AJ7KXOG.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=QCiWuNpIjmE&index=31&list=PL... Previous Video: https://www.youtube.com/watch?v=aG_L3gym0uU&index=29&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 31![]() Play Video |
Dirac Notation Short physical chemistry lecture on Dirac notation in quantum mechanics. Dirac bra-ket notation is a shorthand for various integrals and expressions that appear frequently in quantum mechanics, including overlap integrals, expectation values, and normalization integrals. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/HEg2D3j.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=GHk5C7PNFOc&index=32&list=PL... Previous Video: https://www.youtube.com/watch?v=0Q_KmTOy07E&index=30&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 32![]() Play Video |
Orthogonality Short physical chemistry lecture on orthogonal functions. We are most familiar with the concept of orthogonality between sets of mutually perpendicular vectors. Functions are orthogonal over a given region if the integral of their product is zero over that same range. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/t7wbsrG.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=PHus6stbje0&index=33&list=PL... Previous Video: https://www.youtube.com/watch?v=QCiWuNpIjmE&index=31&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 33![]() Play Video |
Superposition Principle 1: Basis Sets Short physical chemistry lecture on basis sets in the superposition principle. A general wavefunction can be expressed as a linear combination of basis functions which are the eigenfunctions of the Hamiltonian operator. The set of these basis functions combined is referred to as a basis set. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/We2mvj1.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=H7aejrEU8Jo&index=34&list=PL... Previous Video: https://www.youtube.com/watch?v=GHk5C7PNFOc&index=32&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 34![]() Play Video |
Superposition Principle 2: Expectation Values Short physical chemistry lecture on expectation values in the superposition principle. When the wavefunction is expressed as a linear combination of eigenfunctions of an operator, the average value and probabilities of observed values is determined by the coefficients of each eigenfunction. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/65bsi5A.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=f65sIWYGUIg&index=35&list=PL... Previous Video: https://www.youtube.com/watch?v=PHus6stbje0&index=33&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 35![]() Play Video |
Superposition Principle 3: Example Short physical chemistry lecture on an example of the superposition principle. For a linear combination of eigenfunctions of the Hamiltonian, the probability of measuring each energy eigenvalue is proportional to its coefficient squared. The expectation value, or average value, of the energy is a weighted average of all energy values where the coefficients squared are the weights. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/EIrsqtq.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=jw9BHoYsu9k&index=36&list=PL... Previous Video: https://www.youtube.com/watch?v=H7aejrEU8Jo&index=34&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/watch?v=m4bM4djNnwQ&index=1&list=PLm... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 36![]() Play Video |
Commuting Operators Short physical chemistry lecture on the eigenfunctions of commuting operators. If two operators commute then they have the same set of eigenfunctions and vice versa. Commuting operators do not have an uncertainty product relationship between them. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/U9SFOYO.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=GI54KUjUGqc&index=37&list=PL... Previous Video: https://www.youtube.com/watch?v=f65sIWYGUIg&index=35&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 37![]() Play Video |
Time Dependence Short physical chemistry lecture on the time dependence of wavefunctions. For eigenfunctions of the Hamiltonian, the time dependent wavefunction adds a complex exponential to the spatial wavefunction based on its energy. For a superposition, each eigenfunction gets its own complex exponential time component. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/Y6SUOZu.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=ogMwnS-uQSM&index=38&list=PL... Previous Video: https://www.youtube.com/watch?v=jw9BHoYsu9k&index=36&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 38![]() Play Video |
Time Dependence Animation Short physical chemistry lecture showing an animation of time-dependent wavefunctions. Eigenfunctions of the Hamiltonian are stationary states over time, where the probability density is constant. A linear combination of multiple eigenfunctions results in sinusoidal oscillation of the probability density over time. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Link to Graph: https://www.desmos.com/calculator/qk403rhb0p --- Video Links --- Next Video: https://www.youtube.com/watch?v=frIyVxcuVHo&index=39&list=PL... Previous Video: https://www.youtube.com/watch?v=GI54KUjUGqc&index=37&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 39![]() Play Video |
Wavefunction Collapse Short physical chemistry lecture on wavefunction collapse. Before a measurement, a wavefunction is a linear combination of eigenfunctions with probabilities for measurement based on their coefficients. During a measurement, the wavefunction collapses into an eigenfunction, giving a single eigenvalue for the property, and remains in that eigenfunction thereafter. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/K1DILYd.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=xoKDuc5uE5s&index=40&list=PL... Previous Video: https://www.youtube.com/watch?v=ogMwnS-uQSM&index=38&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 40![]() Play Video |
Schrodinger's Cat Short physical chemistry lecture on the Schrodinger's cat thought experiment. If we arrange a situation where the life or death of a cat depends on the state of a quantum particle which is in an equal superposition of two states, according to the Copenhagen interpretation of quantum mechanics, the cat is both alive and dead until we open the box and measure its state. This example of wavefunction collapse demonstrates how non-intuitive the behavior of quantum systems is when applied to macroscopic objects. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/A8ymJB4.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=1Pd9iyD26i8&index=41&list=PL... Previous Video: https://www.youtube.com/watch?v=frIyVxcuVHo&index=39&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 41![]() Play Video |
Correspondence Principle Short physical chemistry lecture on the correspondence principle. Quantum mechanics is a more general theory than classical mechanics, and must reduce to classical mechanics under the limits of systems with high energy, large mass, and/or large length. The quantum model systems for translation, rotation, and vibration reduce to classical, continuous expressions under these limits. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/iW0wFdb.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=Thy9YXnAY2s&index=42&list=PL... Previous Video: https://www.youtube.com/watch?v=xoKDuc5uE5s&index=40&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&index=1&list=PLm... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLLM5kDbCf6... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 42![]() Play Video |
Harmonic Oscillator Model Short physical chemistry lecture on the harmonic oscillator model. Using the potential energy surface of a diatomic molecule, we choose a quadratic potential energy function as our quantum mechanical model of a vibrating diatomic molecule. We must specify the stiffness of the parabola k, and the mass of our system, m. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/q6PuOKt.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=QuI3IWlByqo&index=43&list=PL... Previous Video: https://www.youtube.com/watch?v=Thy9YXnAY2s&index=42&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL4kdvchwcg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 43![]() Play Video |
Classical Harmonic Oscillator 1: Trajectory Short physical chemistry lecture on the trajectory of the classical harmonic oscillator. A classical particle in a quadratic potential energy function will have a time trajectory which is a sinusoidal function whose angular velocity is determined by the spring constant of the parabola k, and the mass of the particle m. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/8Fy3WKn.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=3LxM2VAMVsQ&index=44&list=PL... Previous Video: https://www.youtube.com/watch?v=Thy9YXnAY2s&index=42&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL4kdvchwcg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 44![]() Play Video |
Classical Harmonic Oscillator 2: Energy Short physical chemistry lecture on the energy of the classical harmonic oscillator. Once we've determined the time trajectory of the classical harmonic oscillator, we can use the expressions for kinetic energy and potential energy to show that the total energy is conserved over time, and is determined by the spring constant k and the amplitude of the diplacement A. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/4heXAlX.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=iUwBW4e9n6g&index=45&list=PL... Previous Video: https://www.youtube.com/watch?v=QuI3IWlByqo&index=43&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL4kdvchwcg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 45![]() Play Video |
Reduced Mass Short physical chemistry lecture on reduced mass in the harmonic oscillator. The mass we use for the harmonic oscillator model system is the reduced mass of the two atoms in the diatomic molecule. The reduced mass of two particles is the product of their masses divided by their sum. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/pE7srrK.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=GPM9NYCY0f0&index=46&list=PL... Previous Video: https://www.youtube.com/watch?v=3LxM2VAMVsQ&index=44&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL4kdvchwcg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicL4kdvchwcg... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
V. Harmonic Oscillator | |
Lecture 46![]() Play Video |
Harmonic Oscillator Energy Levels Short physical chemistry lecture on the energy levels of the quantum harmonic oscillator. The harmonic oscillator model system has energy levels which are evenly spaced based on their quantum number n. The spacing between levels depends on the spring constant of the parabola k, and the reduced mass of the two atoms, mu. The ground state n = 0 has non-zero energy, resulting in the zero point vibrational energy (ZPVE). --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/hl1Fm5E.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=MkS1J9eq-Eo&index=47&list=PL... Previous Video: https://www.youtube.com/watch?v=iUwBW4e9n6g&index=45&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL4kdvchwcg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 47![]() Play Video |
Diatomic Infrared Spectra Short physical chemistry lecture on the infrared spectra of diatomic molecules. The selection rule during infrared transitions between vibrational energy levels is that the quantum number change by +1 (absorption) or -1 (emission). The frequency of transition depends on the angular velocity omega, which is determined by the spring constant and reduced mass of the system. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/siwDBcW.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=5oXn8A9K4Mc&index=48&list=PL... Previous Video: https://www.youtube.com/watch?v=GPM9NYCY0f0&index=46&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL4kdvchwcg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 48![]() Play Video |
Anharmonicity and Overtones Short physical chemistry lecture on anharmonicity and overtones. The harmonic oscillator energies and spectra result from a second-order Taylor series around the minimum of a diatomic potential energy surface. When we extend the Taylor series to higher terms, we get anharmonic corrections to the energy levels and spectrum. The magnitude of the deviation depends on the anharmonicity constant xe. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/hYkSyD0.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=gKUdaa4HXkI&index=49&list=PL... Previous Video: https://www.youtube.com/watch?v=MkS1J9eq-Eo&index=47&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL4kdvchwcg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 49![]() Play Video |
Harmonic Oscillator Wavefunctions Short physical chemistry lecture on the wavefunctions of the harmonic oscillator. The wavefunctions of the harmonic oscillator model system are a normalization constant times a Hermite polynomial times a Gaussian function centered at the origin. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Link to graph: https://www.desmos.com/calculator/indbarqddv Notes Slide: http://imgur.com/tShBa6X.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=DX37ZFyKNKM&index=50&list=PL... Previous Video: https://www.youtube.com/watch?v=5oXn8A9K4Mc&index=48&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL4kdvchwcg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 50![]() Play Video |
Even and Odd Functions Short physical chemistry lecture on even and odd functions. Even functions are those such that f(x) = f(-x). Odd functions are those such that f(-x) = -f(-x). The integral over all space of an even function is twice its integral from zero to infinity. The integral over all space of an odd function is zero. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/Aw9g7ZM.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=2gaYU63kvCI&index=51&list=PL... Previous Video: https://www.youtube.com/watch?v=gKUdaa4HXkI&index=49&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 51![]() Play Video |
Harmonic Oscillator Even and Odd Functions Short physical chemistry lecture on using even and odd functions for harmonic oscillator expectation values. Applying the concept of even and odd functions to the wavefunctions of the harmonic oscillator and the momentum and position operators allows us to compute the expectation values of position and momentum for this system without computing any integrals. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/I63Hwio.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=aP1WLAua3aU&index=52&list=PL... Previous Video: https://www.youtube.com/watch?v=DX37ZFyKNKM&index=50&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL4kdvchwcg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/watch?v=m4bM4djNnwQ&index=1&list=PLm... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 52![]() Play Video |
3-D Harmonic Oscillator Short physical chemistry lecture on the 3-dimensional harmonic oscillator. We can extend the harmonic oscillator to 3 dimensions by having a spring constant in each dimension of our potential energy function. The Schrodinger equation can be separated into 3 1-dimensional equations where the total wavefunction is a product and the total energy a sum of these 1-dimensional components. Where symmetry of the spring constants exists, degeneracy in the energy levels results. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/2B34SPX.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=y1PGWVN_WxI&index=53&list=PL... Previous Video: https://www.youtube.com/watch?v=2gaYU63kvCI&index=51&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL4kdvchwcg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 53![]() Play Video |
Polyatomic Molecular Vibrations Short physical chemistry lecture on polyatomic molecular vibrations. For a given molecule of N atoms, there are 3N-6 normal modes of vibration, each with their own frequency. The normal modes are the eigenvectors and the frequencies the eigenvalues of the Hessian matrix. The Hessian matrix is a matrix of second derivatives of the potential energy with respect to displacement of all individual atomic coordinates. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliation. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/mbqSbOX.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=GbWnE4LKOtc&index=54&list=PL... Previous Video: https://www.youtube.com/watch?v=aP1WLAua3aU&index=52&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL4kdvchwcg... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
VI. Rigid Rotor Mechanics | |
Lecture 54![]() Play Video |
Rigid Rotor Model Short physical chemistry lecture on the rigid rotor model. The rigid rotor is a model system for the rotation of diatomic molecules of fixed bond length. The potential energy is zero at the fixed bond length. The kinetic energy is expressed as angular momentum squared divided by moment of inertia. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://i.imgur.com/nzG14z9.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=2BqdkpI__50&index=55&list=PL... Previous Video: https://www.youtube.com/watch?v=y1PGWVN_WxI&index=53&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIlRL7FdtY3... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 55![]() Play Video |
Rotation Operators Short physical chemistry lecture on rotation operators. The wavefunctions of the rigid rotor are best expressed in spherical polar angular coordinates theta and phi. The Laplacian operator must similarly be expressed in terms of the angular momentum operator in spherical coordinates. We also examine the z-component of angular momentum, the Lz operator. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/3Qkiey5.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=BQfJ3A0eTbA&index=56&list=PL... Previous Video: https://www.youtube.com/watch?v=GbWnE4LKOtc&index=54&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIlRL7FdtY3... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 56![]() Play Video |
Rigid Rotor Energy Levels Short physical chemistry lecture on rigid rotor energy levels. The rigid rotor energy levels depend quadratically on the quantum number J, which ranges from zero to infinity. The spacing is determined by the rotational constant B, which is effected by the bond length and reduced mass of the two atoms in our diatomic molecule. The degeneracy of each energy level increases by 2 as the energy increases. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/PwiK1fA.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=l-C03vp6gMk&index=57&list=PL... Previous Video: https://www.youtube.com/watch?v=2BqdkpI__50&index=55&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIlRL7FdtY3... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 57![]() Play Video |
Diatomic Microwave Spectra Short physical chemistry lecture on diatomic microwave spectra. The selection rule for transitions in rotational energy levels is the change in quantum number J is +1 or -1. Energy jumps between successive levels increases linearly as the value of J increases, leading to a spectrum of evenly spaced lines in a microwave region. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/36Tz8SE.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=Y7_ADYrKssU&index=58&list=PL... Previous Video: https://www.youtube.com/watch?v=BQfJ3A0eTbA&index=56&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIlRL7FdtY3... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 58![]() Play Video |
Rovibrational Energy Levels Short physical chemistry lecture on rovibrational energy levels. The energy levels of the harmonic oscillator and rigid rotor model systems combine to give the rovibrational energy levels. These energy levels depend on the rotational and vibrational constants, which depend on the bond length, reduced mass, and spring constant of the diatomic molecule. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/y4qkhB2.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=ELf6rzEQ9kI&index=59&list=PL... Previous Video: https://www.youtube.com/watch?v=l-C03vp6gMk&index=57&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIlRL7FdtY3... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 59![]() Play Video |
Diatomic Rovibrational Spectra Short physical chemistry lecture on diatomic rovibrational spectra. The selection rule for rovibrational absorption is that the change in vibrational quantum number n is +1, and the change in rotational quantum number J is +1 (R branch) or -1 (P branch). The frequency of transition is the fundamental vibrational frequency plus or minus an integer times 2 times the rotational constant. --- All TMP Chem content is 100% free and ad-free for everyon everywhere. All content in created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/cvTgUBE.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=qiTbuKE55Dk&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=Y7_ADYrKssU&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIlRL7FdtY3... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 60![]() Play Video |
Microwave Spectroscopy Example Short physical chemistry lecture showing an example of the use of microwave spectroscopy. Given a microwave spectrum of a diatomic molecule, we can use the peak spacing to determine its rotational constant. If we know the chemical formula, we can use the rotational constant and reduced mass of the atoms to compute the bond length of the diatomic molecule. Here we solve this for the example of carbon monoxide. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/x4A3gWa.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=Lecacm8BBwc&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=ELf6rzEQ9kI&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIlRL7FdtY3... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 61![]() Play Video |
Rotation-Vibration Interaction Short physical chemistry lecture on rotation-vibration interaction. At higher vibrational energy levels, anharmonicity causes an increase in bond length and a decrease in rotational constant. This causes the peak in the R branch of the rovibrational spectrum to be closer together than those in the P branch. The magnitude of this difference is determined by the value of the rotation-vibration interaction constant. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/TGsSJvI.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=v_BbITtV71o&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=qiTbuKE55Dk&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIlRL7FdtY3... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/watch?v=m4bM4djNnwQ&index=1&list=PLm... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 62![]() Play Video |
Centrifugal Distortion Short physical chemistry lecture on centrifugal distortion. As the rotational energy level increases, centrifugal forces cause a slight increase in the bond length of a diatomic molecule. This increases the moment of inertia, decreasing the rotational constant. The ideal rigid rotor has equally spaced spectral peaks, but centrifugal distortion causes the separation to decrease slightly as J increases. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/C1acwn2.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=WRZt0BCotos&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=Lecacm8BBwc&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIlRL7FdtY3... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 63![]() Play Video |
Rigid Rotor Wavefunctions Short physical chemistry lecture on the rigid rotor wavefunctions. The wavefunctions of the rigid rotor system are the spherical harmonic functions. The spherical harmonics depend on two quantum numbers, l and m. L is an integer from 0 to infinity. M is an integer from -l to +l. The spherical harmonics are a normalization constant times an associated Legendre polynomial times a complex exponential. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/3VLolBh.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=V_pcuYoLxFI&index=64&list=PL... Previous Video: https://www.youtube.com/watch?v=v_BbITtV71o&index=62&list=PL... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIlRL7FdtY3... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 64![]() Play Video |
Orthonormality of Spherical Harmonics Short physical chemistry lecture on the orthonormality of spherical harmonics. The wavefunctions of the rigid rotor are the spherical harmonics, which depend on the quantum numbers J and m. These functions are orthonormal, as they are both normalized and orthogonal. The integral of psi_star psi over all values of theta and phi is 1 if J and m are the same for both functions, and 0 otherwise. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/rt5lgYq.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=B82pEpoDE_k&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=WRZt0BCotos&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIlRL7FdtY3... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 65![]() Play Video |
Angular Momentum Eigenvalues Short physical chemistry lecture on angular momentum eigenvalues. The wavefunctions of the rigid rotor are the spherical harmonics, which are eigenfunctions of the L^2 and Lz operators. The spherical harmonics depend on quantum numbers J and m. The eigenvalues of L^2 are hbar^2 J(J+1). The eigenvalues of Lz are hbar m. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/lVMqzKR.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=phIc-an6B2A&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=V_pcuYoLxFI&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIlRL7FdtY3... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
VII. The Hydrogen Atom | |
Lecture 66![]() Play Video |
Hydrogen Atom Model Short physical chemistry lecture on the hydrogen atom model. The hydrogen atom model system has a proton fixed at the origin and an electron free to move in 3 dimensions. The Hamiltonian operator is the kinetic energy and potential energy of the electron. The potential energy is a Coulomb potential between the electron and proton. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/CruEB37.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=loNZJwRGys0&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=B82pEpoDE_k&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLqbzYEN863... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 67![]() Play Video |
Hydrogen Atom Energy Levels Short physical chemistry lecture on hydrogen atom energy levels. The energy levels of the hydrogen atom depend inverse quadratically on the principal quantum number n. The proportionality constant is the negative Rydberg constant. The degeneracy of each level depends quadratically on n, which starts at 1 and goes up to infinity. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/JxOUrBt.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=WUTgyBruBa8&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=phIc-an6B2A&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLqbzYEN863... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 68![]() Play Video |
Hydrogen Atom Radial Wavefunctions Short physical chemistry lecture on hydrogen atom radial wavefunctions. The radial portion of the wavefunctions of the hydrogen atom model is a normalization constant times the associated Laguerre polynomials times a decaying exponential. The function depends on the principal quantum number n and the orbital angular momentum quantum number l. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/goswGU0 --- Video Links --- Next Video: https://www.youtube.com/watch?v=40ftYOfsEDU&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=loNZJwRGys0&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLqbzYEN863... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 69![]() Play Video |
Hydrogen Atom Total Wavefunctions Short physical chemistry lecture on hydrogen atom total wavefunctions. The total wavefunctions of the hydrogen atom are the atomic orbital functions. In spherical polar coordinates, they are a radial function times the spherical harmonics. The values of the quantum number n and l determine the shape of the orbital, with familiar names like 1s, 2s, 2p, 3s, 3p, and 3d. The quantum number m determines the orientation in space of the function. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/nA4HC5v.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=Rr3MGp0ziSo&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=WUTgyBruBa8&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLqbzYEN863... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 70![]() Play Video |
Hydrogen Atomic Orbital Nodes Short physical chemistry lecture on hydrogen atomic orbital nodes. A node is a location where the wavefunction is zero, thus there is no electron density. A radial node is a value of r at which all points have no density. An angular node is a value of theta and/or phi where all points have no density. The quantum numbers n and l determine the number of radial and angular nodes. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/h6kDbcQ --- Video Links --- Next Video: https://www.youtube.com/watch?v=wJCEskknrtI&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=40ftYOfsEDU&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLqbzYEN863... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 71![]() Play Video |
Hydrogen Orbital Eigenvalues Short physical chemistry lecture on hydrogen atomic orbital eigenvalues. The hydrogen atom atomic orbitals have three quantum numbers, n, l, and m which identify each unique orbital. The value of n determines the energy and degeneracy of each shell. The value of l determines the orbital angular momentum (s, p, d, etc). The value of m determines the z-component of angular momentum. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/3VC6Jis.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=onmkfIKiReo&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=Rr3MGp0ziSo&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLqbzYEN863... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 72![]() Play Video |
Hydrogen Atom Radius Short physical chemistry lecture on measures of the hydrogen atom "radius". The Bohr radius is 0.529 Angstroms, or a_o. The expectation value of the radius of the 1s hydrogen orbital is 1.5 a_0. The most probable value of the radius is 1.0 a_o. Alternatively, we can compute a probability radius, where a certain percent of the electron density falls inside the given radius. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/jlBTi2X.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=JHZopK6e-tE&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=wJCEskknrtI&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLqbzYEN863... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 73![]() Play Video |
Hydrogen Atom Radial Wavefunction Animation Short physical chemistry lecture showing an animation of the hydrogen atom radial wavefunctions. The radial distribution function of electron density in the hydrogen atomic orbitals is the radial wavefunction squared times r squared. Each set of the quantum numbers n and l results in a unique radial distribution versus radius. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Link to Graph: https://www.desmos.com/calculator/qtg1iagj1m --- Video Links --- Next Video: https://www.youtube.com/watch?v=9OZ6d3WT_fg&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=onmkfIKiReo&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLqbzYEN863... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 74![]() Play Video |
Virial Theorem Short physical chemistry lecture on the virial theorem for atoms and molecules. The virial theorem relates the expectation values of potential energy and kinetic energy in atoms and molecules. We calculate that for the hydrogen 1s orbital, as for all atomic and molecular wavefunctions, their ratio is -2. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/42LEuGo.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=ubv0DTL_0bg&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=JHZopK6e-tE&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLqbzYEN863... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 75![]() Play Video |
Zeeman Effect Short physical chemistry lecture on the Zeeman magnetic effect. In the absence of a magnetic field, hydrogen atom energy levels depend only on the principal quantum number n. A magnetic field interacts with the magnetic dipole of the electron, splitting the energies based on the quantum number m. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/ECCP7EG.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=dRSI4hft0DY&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=9OZ6d3WT_fg&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLqbzYEN863... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 76![]() Play Video |
Electron Spin Short physical chemistry lecture on electron spin. Electrons which travel at the same speed through an inhomogenous magnetic field will result in two different trajectories. This is explained by electrons having an intrinsic spin angular momentum of 1/2 hbar, which can either align itself towards or against the z-axis. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/QjrzFIT.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=ZW9HJRbJHoY&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=ubv0DTL_0bg&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLqbzYEN863... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 77![]() Play Video |
Spin-Orbit Coupling Short physical chemistry lecture on spin-orbit coupling. Orbital angular momentum L can couple with spin angular momentum S to give the total angular momentum J through spin orbit coupling. The values of J go from |L+S| to |L-S|, with values of m_J ranging from +J to -J. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/dTQRY97.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=KNOKj0ekfdE&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=dRSI4hft0DY&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLqbzYEN863... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 78![]() Play Video |
Hydrogen Atom Term Symbols Short physical chemistry lecture on hydrogen atom term symbols. Distinct electronic states are represented by term symbols, which denote their values of spin, orbital, and total angular momentum; S, L, and J. For hydrogen (one electron), S = 1/2, L = l of the orbital, and J = |L+1/2|, |L-1/2|. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/1ajdLCu.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=QMKpSY5z-N0&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=ZW9HJRbJHoY&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLqbzYEN863... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 79![]() Play Video |
Hydrogen Atom Spectrum Short physical chemistry lecture on the hydrogen atom spectrum. The selection rules for energy level transitions in the hydrogen atom are that deltaS = 0; deltaL = +1, 0, or -1; and deltaJ = +1, 0, or -1. There is no restriction on delta_n, giving the many series of lines which give rise to the Rydberg formula. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/BO3IF90.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=KwdrQZlclDk&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=KNOKj0ekfdE&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLqbzYEN863... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 80![]() Play Video |
Helium Atom Hamiltonian Short physical chemistry lecture on the helium atom Hamiltonian. The Hamiltonian operator of the helium atom include the kinetic energy of the nucleus and 2 electrons as well as the potential energy of the Coulomb potential between all 3 pairs of charged particles. The electron repulsion term makes this non-separable, meaning it cannot be solved exactly. We need approximate methods to solve for the energy of the helium atom. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is entirely created by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/LUsA3UJ.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=l7n8gQHHFyg&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=QMKpSY5z-N0&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLqbzYEN863... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
VIII. Approximation Methods | |
Lecture 81![]() Play Video |
Variational Principle Short physical chemistry lecture on the variational principle. The variational principle states that the energy of any approximate wavefunction is greater than or equal to the energy of the true ground-state wavefunction. The lower the energy, the better the approximation to the true ground-state. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/oAwpdOn.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=WJekoIaXrJI&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=KwdrQZlclDk&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIBR4N5A6Ps... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 82![]() Play Video |
Variational Principle Example Short physical chemistry lecture on an example application of the variational method. By using a Gaussian function for the harmonic oscillator, we can treat the exponent alpha as a parameter for the variational method. We compute the energy as a function of the parameter, and find the minimum energy with respect to the parameter to give the best approximation to the ground state energy and wavefunction. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/ibu45AM.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=LQmpuEm778E&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=l7n8gQHHFyg&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIBR4N5A6Ps... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 83![]() Play Video |
Linear Variational Method Short physical chemistry lecture on the linear variational method. The linear variational method uses a trial wavefunction which is a linear combination of basis functions, with the coefficients as the variational parameters. Minimizing the energy with respect to the parameters results in the matrix Schrodinger equation, which can be solved by using the secular determinant. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/A9mQiEg.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=XcDDC-gXXDc&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=WJekoIaXrJI&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIBR4N5A6Ps... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 84![]() Play Video |
Secular Determinant Short physical chemistry lecture on a simplification of the secular determinant for 2 basis functions. The linear variational method applied to a trial wavefunction with 2 basis functions leads to a straightforward interpretation of the energy levels. In the absence of coupling, each energy level is the energy of each basis function. Coupling causes the states to mix and the energies to diverge further away from one another. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/HtQM8nx.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=3_KtxQPylVM&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=LQmpuEm778E&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIBR4N5A6Ps... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 85![]() Play Video |
Linear Variational Example Short physical chemistry lecture showing an example application of the linear variational method. The linear variational method applied to the particle in a slanted box leads to an energy expression of the particle in a box wavefunctions plus half the magnitude of the slant plus or minus a coupling element based on the slope of the slant. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/cTCCWTM.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=Scv--cfY0xw&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=XcDDC-gXXDc&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIBR4N5A6Ps... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
IX. Perturbation Theory | |
Lecture 86![]() Play Video |
Perturbation Theory Short physical chemistry lecture on perturbation theory. Perturbation theory separates a system for which we cannot solve the Schrodinger equation exactly into a component we can solve and a component we cannot. The reference system gives zeroth order wavefunctions and energies. The perturbation gives a series of corrections for both up to a chosen order. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/XCb969L.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=49NV66BxE9c&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=3_KtxQPylVM&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIBR4N5A6Ps... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 87![]() Play Video |
Perturbation Theory Derivation Short physical chemistry lecture on the derivation of the 1st order perturbation theory energy. Using the Schrodinger equation and the Hamiltonian with an adjustable perturbation parameter lambda, we can derive expressions for each order of perturbation theory. Here we derive the expression for the first order energy correction. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/MInsrfo.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=B4fpfhCC_cM&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=Scv--cfY0xw&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIBR4N5A6Ps... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 88![]() Play Video |
Perturbation Theory Example Short physical chemistry lecture on an example application of perturbation theory. The first order perturbation theory energy correction to the particle in a box wavefunctions for the particle in a slanted box adds half the slant height to each energy level. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/sAk6adi.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=93S-9Izr0nI&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=49NV66BxE9c&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicIBR4N5A6Ps... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 89![]() Play Video |
Atomic Units Short physical chemistry lecture on atomic units. Many quantities which frequently appear in atomic and molecular calculations would be more convenient in an alternative unit system. In atomic units, the mass of the electron, its charge, hbar, 4pi epsilon_o, and the Bohr radius are set equal to one. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/Y593zFv.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=tcfNNGGjS2o&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=B4fpfhCC_cM&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 90![]() Play Video |
Helium Atom Energy Approximations Short physical chemistry lecture on approximations to the helium atom energy. Using various variational and perturbational methods, we look at many different approximations to the ground state energy of the helium atom. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/YRTsRfb.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=jRnUX7Z7fsw&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=93S-9Izr0nI&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
X. Many-Electron Atoms & Hartree-Fock Method | |
Lecture 91![]() Play Video |
Hartree-Fock Helium Atom Short physical chemistry lecture on the Hartree-Fock procedure for the helium atom. We start with an initial guess wavefunction, which generates an effective mean-field operator. The mean-field operator generates a new wavefunction. This cycle iterates until the wavefunction and the energy stops changing, reaching a self-consistent field (SCF). --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/Qb0B1d7.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=Gd3x46Wth8s&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=tcfNNGGjS2o&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 92![]() Play Video |
Hartree-Fock Helium Energy Short physical chemistry lecture on the Hartree-Fock energy of the helium atom. The energy of the helium atom under the Hartree-Fock approximation is the one-electron energy of each electron plus the Coulomb repulsion of the two electrons. The ionization potential is equal to the orbital energy of each electron. The total atomic energy is not equal to a sum of the orbital energies, which double counts electron repulsions. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/pizfrNo.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=O62wmfcbL2Q&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=jRnUX7Z7fsw&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 93![]() Play Video |
Antisymmetry Principle Short physical chemistry lecture on the antisymmetry principle for electons. The wavefunction of any atom or molecule must switch sign when two electrons are exchanged. This anti-symmetry principle results in a total wavefunction which is a Slater determinant. This is the physical origin of the Pauli exclusion principle, which makes the wavefunction go to zero when two electrons are placed in the same spin orbital. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/ASNT4X0.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=ASPuNKrCzDE&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=Gd3x46Wth8s&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 94![]() Play Video |
Slater Determinants Short physical chemistry lecture on Slater determinant wavefunctions. To satisfy the anti-symmetry principle, the wavefunction of atoms and molecules is expressed as a Slater determinant, in which all possible combinations of electrons and orbitals are included. Exchanging any two electrons will change the sign of the wavefunction. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/KVKrcYu.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=aSymTSplN08&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=O62wmfcbL2Q&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 95![]() Play Video |
Hartreee-Fock Atomic Energy Short physical chemistry lecture on the Hartree-Fock energy of atoms. The Hartree-Fock energy of atoms depends on one-electron and two-electron terms. Each electron has one-electron energy, its kinetic energy and nuclear attraction. Each pair of electrons has two-electron energy, Coulomb repulsion and exchange interaction. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/f60vQur.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=ZGb68b8wpEQ&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=ASPuNKrCzDE&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 96![]() Play Video |
Hartree-Fock Operators Short physical chemistry lecture on Hartree-Fock operators. Hartree-Fock theory has several operators. One-electron operators include the kinetic energy operator and the nuclear attraction operator. Two-electron operators include the Coulomb and exchange operators. The two-electron operators combine to form the mean-field operator. The one-electron operators plus the mean field operator combine to form the Fock operator. electron orbitals are eigenfunctions of the Fock operator, with the orbital energy as the eigenvalue. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/bqIS9cG.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=bDizx-xbNso&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=aSymTSplN08&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 97![]() Play Video |
Hartree-Fock-Roothaan Equations Short physical chemistry lecture on the Hartree-Fock-Roothaan equations for atoms. When we use a basis set of atomic orbitals for the linear variational method, the Hartree-Fock equations become the Hartree-Fock-Roothaan equations. Solving FC = ESC for the orbitals gives the energies of occupied and virtual spin orbitals of an atom. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/HcHWaLp.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=i8PC8ONMrpg&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=ZGb68b8wpEQ&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 98![]() Play Video |
Hartee-Fock Spin Short physical chemistry lecture on spin in Hartree-Fock theory. Once we account for the spin of electrons, all one-electron energy terms remain, as do all Coulomb terms. The exchange terms only remain between pairs of same spin electrons. This leads to a simplified expression for the Hartree-Fock atomic energy. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/xcM0suA.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=oU1zO2bPPB4&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=bDizx-xbNso&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 99![]() Play Video |
Post Hartree-Fock Methods Short physical chemistry lecture on post-Hartree-Fock methods for atomic energies. The accuracy of an electronic structure calculation depends on two factors: the size of the atomic orbital basis set, and the accuracy of the electron repulsion method. Basis sets lie on a continuum from the minimal basis set to the complete basis set. Electron repulsion methods lie on a continuum from simplex to complex started at Hartree-Fock and ending at full Configuration Interaction. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/nKgRdV3.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=owni3aWJowY&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=i8PC8ONMrpg&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 100![]() Play Video |
Atomic Electron Configurations Short physical chemistry lecture on electron configurations for atoms. Atoms fill their electron orbitals according to the Aufbau principle, from lowest energy to highest, with a maximum of 2 opposite-spin electrons in each spatial orbital. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/WiTDQhv.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=Z7NbFb0mMTc&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=oU1zO2bPPB4&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 101![]() Play Video |
Electron Configuration Exceptions Short physical chemistry lecture on exceptions to atomic electron configuration rules. Transition metals with d4 and d9 configurations prefer to instead promote an electron from the s block to make their valence shell consist of half-full and/or full subshells. This includes chromium, copper, molybdenum, and silver. Also of interest are transition metal cations, which lose their s electrons prior to their d electrons. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/H05MK9a.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=dhARbw8cdDE&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=owni3aWJowY&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 102![]() Play Video |
Atomic Term Symbols Short physical chemistry lecture on atomic term symbols. Distinct electronic states of atoms are represented by term symbols. Each term symbol indicates the state's value of spin, orbital, and total angular momentum: S, L, and J. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/qjT3YB5.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=doC9Z2S7lm8&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=Z7NbFb0mMTc&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 103![]() Play Video |
Term Symbols Example 1 Short physical chemistry lecture on how to compute term symbols for an atom (example 1). A ground state carbon atom has term symbols 1D2, 3P2, 3P1, 3P0, and 1S0. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/RGI6SH8.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=Gh6u0ER733w&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=dhARbw8cdDE&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 104![]() Play Video |
Term Symbols Example 2 Short physical chemistry lecture on how to compute term symbols for an atom (example 2). A ground state atom with a d9 valence configuration would have term symbols of 2D5/2 and 2D3/2. --- Al TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/FiaF0jW.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=YyFD3B4gjBk&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=doC9Z2S7lm8&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 105![]() Play Video |
Term Symbols Example 3 Short physical chemistry lecture on how to compute term symbols for an atom (example 3). An excited state beryllium atom with a 1s2 2s1 3p1 configuration would have term symbols of 3P2, 3P1, 3P0, and 1P1. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/uxf80bJ.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=IuCUiazyaHU&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=Gh6u0ER733w&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 106![]() Play Video |
Hund's Rules Short physical chemistry lecture on Hund's rules for term symbol energies. The term symbols that have the lowest energy are those with the largest spin angular momentum S. Among those with the same S, the largest orbital angular momentum L is most stable. The stability versus J depends on how filled the subshell is. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/xkwYhKd.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=kee9p1_46Fs&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=YyFD3B4gjBk&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 107![]() Play Video |
Atomic Spectra Short physical chemistry lecture on atomic spectra. The selection rules for transitions between electronic states is that deltaS = 0; deltaL = +1, 0, or -1; and deltaJ = +1, 0, or -1. Transitions where L or J start and end at zero are also forbidden. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/6a48Hpa.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=BBoE6NRRZ8k&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=IuCUiazyaHU&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicI5IG5X8hRR... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 108![]() Play Video |
Hydrogen Molecule Hamiltonian Short physical chemistry lecture on the hydrogen molecule Hamiltonian operator. The Hamiltonian for the hydrogen molecule includes the kinetic energy of each of the two nuclei and two electrons. The potential energy is the Coulomb attraction and repulsion between pairs of nuclei and electrons. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/QfFxDTT.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=UGB2psWD69s&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=kee9p1_46Fs&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLZWxTcr_XW... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 109![]() Play Video |
Born-Oppenheimer Approximation Short physical chemistry lecture on the Born-Oppenheimer approximation for atoms and molecules. Nuclei weigh much more than electrons, and thus move much more slowly. The Born-Oppenheimer approximation says that the nuclei are fixed in their positions with zero kinetic energy while solving for electronic wavefunctions. The electrons provide a potential energy surface which the nuclei feel as they move. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/KeKmcKc.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=cc4CZCjom6A&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=BBoE6NRRZ8k&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLZWxTcr_XW... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 110![]() Play Video |
Hydrogen Molecule-Ion 1: Energy Short physical chemistry lecture on the energies of the hydrogen molecule-ion. Using a 1s orbital centered at each hydrogen atom as a basis set, there are two states which give the energy versus interatomic distance. The lower energy state gives the familiar bound potential energy surface, with the minimum energy at the bond distance. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/Beim8Xe.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=hr05jLHAaLg&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=UGB2psWD69s&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLZWxTcr_XW... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 111![]() Play Video |
Hydrogen Molecule-Ion 2: Orbitals Short physical chemistry lecture on the orbitals of the hydrogen molecule-ion. The two molecular orbitals of the hydrogen molecule-ion result in one bonding and one anti-bonding orbital. Electron density accumulates between the nuclei in the bonding orbital, and depletes between the nuclei in the anti-bonding orbital. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/QbSIPvx.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=nKALF5BXtbs&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=cc4CZCjom6A&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLZWxTcr_XW... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 112![]() Play Video |
Molecular Orbital Angular Momentum Short physical chemistry lecture on molecular orbital angular momentum. The molecular orbitals of homonuclear diatomic molecules are eigenfunctions of the Lz operator the magnitude of their orbital angular momentum quantum number determines whether the orbital is labeled as sigma, pi, delta, etc. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/NsdV4Ae.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=Q8ja0Xu8nWQ&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=hr05jLHAaLg&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLZWxTcr_XW... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 113![]() Play Video |
Molecular Orbital Inversion Symmetry Short physical chemistry lecture on molecular orbital inversion symmetry. The molecular orbitals of homonuclear diatomic molecules are eigenfunctions of the inversion operator. The eigenvalue is either +1 or -1. Those with +1 are labelled gerade, symmetric with respect to inversion. Those with -1 are labelled ungerade, antisymmetric with respect to invesrion. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/O4g4GoS.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=1-UIdbGY3nQ&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=nKALF5BXtbs&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLZWxTcr_XW... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 114![]() Play Video |
Hydrogen Molecular Orbital Diagram Short physical chemistry lecture on the molecular orbital diagram of the hydrogen molecule. The 1s orbitals of each hydrogen atom combine to form a low energy occupied sigma_g bonding orbital and a high energy unoccupied sigma^star_u anti-bonding orbital. The ground state of h2 is this 1sigma_g^2. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/dMgXFev.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=7ItAyG_m7jA&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=Q8ja0Xu8nWQ&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLZWxTcr_XW... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 115![]() Play Video |
LCAO-MO Theory Short physical chemistry lecture on linear combination of atomic orbitals In homonuclear diatomic molecules, the 1s, 2s, and 2pz orbitals combine to form sigma_g bonding and sigma_u^star anti-bonding molecular orbitals.The 2px and 2py combine to form pi_u bonding and pi_g^star anti-bonding orbitals. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/FdgJTKQ.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=k33zQLpCnuM&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=1-UIdbGY3nQ&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLZWxTcr_XW... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
XI. Diatomic Molecules | |
Lecture 116![]() Play Video |
Diatomic Molecular Orbital Diagrams Short physical chemistry lecture on the electron configurations of homonuclear diatomic molecules. The atomic orbitals of atoms in homonuclear diatomic molecules overlap to form distinct sets of molecular orbitals. The orbitals are filled according to the Aufbau principle, giving rise to the electron configurations of these molecules. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/Vsbll5H.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=Tx-aBZnsjZU&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=7ItAyG_m7jA&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLZWxTcr_XW... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 117![]() Play Video |
Bond Order Short physical chemistry lecture on bond order in diatomic molecules. Every electron in a bonding molecular orbital contributes + 1/2 towards the bond order. Every electron in an anti-bonding molecular orbital contributes - 1/2 towards the bond order. Bond order represents the number of bonds in a diatomic molecule. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/Jst2peB.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=ww6HEEXwrbk&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=k33zQLpCnuM&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLZWxTcr_XW... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 118![]() Play Video |
Diatomic Term Symbols Short physical chemistry lecture on the term symbols of homonuclear diatomic molecules. Distinct electronic states in homonuclear diatomic molecules are represented by term symbols. Term symbols indicate the value of spin angular momentum S and orbital angular momentum Lambda for a given state. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/JrQEQT2.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=r1bOcVTFaNQ&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=Tx-aBZnsjZU&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLZWxTcr_XW... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 119![]() Play Video |
Total Wavefunction Symmetry Short physical chemistry lecture on the inversion symmetry of diatomic wavefunctions. Each individual molecular orbital in a homonuclear diatomic molecule is either symmetric (gerade) or antisymmetric (ungerade) with respect to inversion. If there are an even number of ungerade occupied spin orbitals, the total wavefunction symmetry is gerade. If there are an odd number, the total wavefunction symmetry is ungerade. --- All TMP Chem content is 100% free and ad-free for everyone everywhere. All content is created entirely by Trent Parker without any external affiliations. If you would like to support my work, you may do so through the PayPal link in this description. There is no expectation of donation and no ill will if you choose not to or cannot make a donation. There is only gratitude towards those who choose to do so. To request private tutoring, send an email to the address below with the subject line "tutoring" to set up an initial consultation. Notes Slide: http://imgur.com/X7Clo1l.png --- Video Links --- Next Video: https://www.youtube.com/watch?v=Eo1AiP770ds&list=PLm8ZSArAXi... Previous Video: https://www.youtube.com/watch?v=ww6HEEXwrbk&list=PLm8ZSArAXi... Course Intro: https://www.youtube.com/watch?v=HC81oYe43DI&list=PLm8ZSArAXi... Chapter Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicLZWxTcr_XW... Course Playlist: https://www.youtube.com/playlist?list=PLm8ZSArAXicL3jKr_0nHH... Course Review: https://www.youtube.com/playlist?list=PLm8ZSArAXicLTRn3cJyyU... Channel Guide: https://youtu.be/XwvU_LdMdos Private Tutoring: https://youtu.be/iHhOWL4G-r0 Support This Channel: https://youtu.be/JvZhTStEwkQ --- Social Media Links --- Email: tmpchemistry@gmail.com Facebook: https://www.facebook.com/tmpchem Twitter: https://www.twitter.com/tmpchem LinkedIn: https://www.linkedin.com/in/tmpchem Imgur: https://tmpchem.imgur.com GitHub: https://www.github.com/tmpchem PayPal: https://www.paypal.com/us/cgi-bin/webscr?cmd=_flow&SESSION=Z... --- Equipment used --- Microphone: Blue Yeti USB Microphone Drawing program: Autodesk Sketchbook Express Screen capture and video editing: Corel Visual Studio Pro X6 |
Lecture 120![]() Play Video |
sp Hybridization Physical chemistry microlecture on sp hybridization in linear molecules. |
Lecture 121![]() Play Video |
sp2 Hybridization Physical chemistry microlecture on sp2 hybridization in trigonal planar molecules. |
Lecture 122![]() Play Video |
sp3 Hybridization Physical chemistry microlecture on sp3 hybridization in tetrahedral molecules. |
Lecture 123![]() Play Video |
Lone Pair Hybridization Physical chemistry microlecture on hybridization in polyatomic molecules with lone pair orbitals. |
Lecture 124![]() Play Video |
Walsh Diagrams Physical chemistry microlecture on Walsh diagrams for orbital energies versus intramolecular coordinate distortion. |
Lecture 125![]() Play Video |
Huckel Theory Physical chemistry microlecture on the basics of a Huckel theory calculation for the pi system of planar unsaturated hydrocarbons. |
Lecture 126![]() Play Video |
Pi Resonance Physical chemistry microlecture on Huckel theory calculations for predicting the resonance energy of conjugated polyenes. |
Lecture 127![]() Play Video |
Aromaticity Physical chemistry microlecture on the use of Huckel theory to predict the stabilization of aromatic molecules due to aromaticity. |
Lecture 128![]() Play Video |
Symmetry Websites Physical chemistry microlecture introducing helpful websites for practicing symmetry and group theory concepts in chemistry. Symmetry @ Otterbein: symmetry.otterbein.edu Character Tables: symmetry.jacobs-university.de |
Lecture 129![]() Play Video |
Symmetry Operations Physical chemistry microlecture on the basic symmetry operations of molecules including identity, inversion, reflection, rotation, and improper rotation. Symmetry @ Otterbein: symmetry.otterbein.edu Character Tables: symmetry.jacobs-university.de |
Lecture 130![]() Play Video |
Symmetry Elements Physical chemistry microlecture on the basic symmetry elements of molecules including identity, inversion center, plane of reflection, axis of rotation, and improper axis of rotation. Symmetry @ Otterbein: symmetry.otterbein.edu Character Tables: symmetry.jacobs-university.de |
Lecture 131![]() Play Video |
Groups Physical chemistry microlecture on the definition and requirements of a group in group theory. Symmetry @ Otterbein: symmetry.otterbein.edu Character Tables: symmetry.jacobs-university.de |
Lecture 132![]() Play Video |
Point Groups Physical chemistry microlecture introducing the point groups and their symmetry elements for molecules. Symmetry @ Otterbein: symmetry.otterbein.edu Character Tables: symmetry.jacobs-university.de |
Lecture 133![]() Play Video |
Point Group Examples Physical chemistry microlecture giving many examples of the point groups of common molecules. Symmetry @ Otterbein: symmetry.otterbein.edu Character Tables: symmetry.jacobs-university.de |
Lecture 134![]() Play Video |
Point Group Flow Chart Physical chemistry microlecture on determining the point group of a molecule from its symmetry elements. Symmetry @ Otterbein: symmetry.otterbein.edu Character Tables: symmetry.jacobs-university.de |
Lecture 135![]() Play Video |
Group Multiplication Tables Physical chemistry microlecture on the products of operators for the C2h point group as a demonstration that symmetry operations form a group. Symmetry @ Otterbein: symmetry.otterbein.edu Character Tables: symmetry.jacobs-university.de |
Lecture 136![]() Play Video |
Symmetry Operator Matrices Physical chemistry microlecture on determining the matrix operator representations of various symmetry operators in the D2h point group. Symmetry @ Otterbein: symmetry.otterbein.edu Character Tables: symmetry.jacobs-university.de |
Lecture 137![]() Play Video |
Irreducible Representations Physical chemistry microlecture on irreducible representations of molecular point groups. Symmetry @ Otterbein: symmetry.otterbein.edu Character Tables: symmetry.jacobs-university.de |
Lecture 138![]() Play Video |
Character Tables 1 Physical chemistry microlecture introducing character tables for molecular point groups and the meaning of the labels of irreducible representations. Symmetry @ Otterbein: symmetry.otterbein.edu Character Tables: symmetry.jacobs-university.de |
Lecture 139![]() Play Video |
Character Tables 2 Physical chemistry microlecture on character tables of Abelian and non-Abelian molecular point groups. Symmetry @ Otterbein: symmetry.otterbein.edu Character Tables: symmetry.jacobs-university.de |
Lecture 140![]() Play Video |
Determining Irreps Physical chemistry microlecture of determining the irreducible representation of a set of molecular orbitals in a molecule with symmetry. Symmetry @ Otterbein: symmetry.otterbein.edu Character Tables: symmetry.jacobs-university.de |
Lecture 141![]() Play Video |
Generating Operators Physical chemistry micrlecture on using generating operators to construct symmetry-adapted linear combinations of atomic orbitals. Symmetry @ Otterbein: symmetry.otterbein.edu Character Tables: symmetry.jacobs-university.de |
Lecture 142![]() Play Video |
Group Theory Example Physical chemistry microlecture demonstrating how to determine the irreducible representation and number of IR and Raman active normal modes for a symmetric molecule. Symmetry @ Otterbein: symmetry.otterbein.edu Character Tables: symmetry.jacobs-university.de |
Lecture 143![]() Play Video |
Nuclear Spin Physical chemistry microlecture discussing the operators and eigenvalues for nuclear spin angular momentum. |
Lecture 144![]() Play Video |
Magnetic Moments Physical chemistry microlecture on the magnetic dipole generated by the spin angular momentum of a nucleus. |
XII. Nuclear Magnetic Resonance | |
Lecture 145![]() Play Video |
Nuclear Magnetic Resonance Physical chemistry microlecture on the energy levels of nuclear spin states in a magnetic field. |
Lecture 146![]() Play Video |
NMR Spectrometer Physical chemistry microlecture introducing the concept of measuring a resonance frequency with an NMR spectrometer. |
Lecture 147![]() Play Video |
Magnetic Shielding Physical chemistry microlecture discussing magnetic shielding and how it shifts NMR absorption frequencies. |
Lecture 148![]() Play Video |
Chemical Shift Physical chemistry microlecture on the connection between magnetic shielding, chemical shift, and the chemical environment. |
Lecture 149![]() Play Video |
Spin-Spin Coupling Physical chemistry microlecture discussing the physics behind coupling constants in NMR spectra. |
Lecture 150![]() Play Video |
First Order Spectra Physical chemistry microlecture discussing the conditions under which first-order perturbation theory is accurate for calculating the spin-spin coupling between NMR transition frequencies. |
Lecture 151![]() Play Video |
Chemical Equivalence Physical chemistry microlecture deriving why chemically equivalent protons do not split each other on NMR spectra. |
Lecture 152![]() Play Video |
The n+1 Rule Physical chemistry microlecture on the origin of the n+1 rule for coupling between a proton and a set of chemically equivalent protons. |
Lecture 153![]() Play Video |
Second Order Spectra Physical chemistry microlecture on the use of the linear variational method to calculate spin-spin coupling when first-order perturbation theory fails. |
XIII. Particle in a Ring | |
Lecture 154![]() Play Video |
Particle in a Ring Model Physical chemistry microlecture on the particle in a ring model system, potential energy, and Hamiltonian. |
Lecture 155![]() Play Video |
Particle in a Ring Energies Physical chemistry microlecture on the particle in a ring boundary condition and energy levels. |
Lecture 156![]() Play Video |
Particle in a Ring Wavefunctions Physical chemistry microlecture on the particle in a ring wavefunctions and normalization. |
Lecture 157![]() Play Video |
Huckel's Rule Physical chemistry microlecture on the emergence of Huckel's Rule from the energy levels of the particle in a ring model system. |
Lecture 158![]() Play Video |
UV-Vis Spectrum of Aromatics Physical chemistry microlecture on the application of the particle in a ring model system energy levels to prediction of the UV-Vis absorption spectrum of aromatic hydrocarbons. |
Lecture 159![]() Play Video |
Particle in a Ring Eigenvalues Physical chemistry microlecture on the eigenvalues of the Hamiltonian and Lz angular momentum operators for the particle in a ring model system. |