Lecture Description
Physical chemistry microlecture on the temperature and pressure dependence of coexistence curves and the Clapeyron equation.
Course Index
- Introduction
- Ideal Gas Equation
- van der Waals Gas Equation
- Gas Equation Example
- Virial Equation of State
- Molecular Interaction Functions
- Critical Point
- Reduced Properties
- Gas Properties Review
- Energy Quantization
- Boltzmann Factor
- Average Ensemble Energy
- Partition Function Example 1
- Partition Function Example 2
- Partition Function Example 3
- Molecular Partition Function 1
- Molecular Partition Function 2
- Translational Partition Function
- Rotational Partition Function
- Statistical Mechanics Review
- First Law
- Pressure-Volume Work
- State and Path Functions
- Reversible Processes
- Isothermal Processes
- Adiabatic Processes
- Adiabatic / Isothermal Comparison
- Microscopic Heat and Work
- Enthalpy
- Enthalpy Example
- Heat Capacity
- Transition Enthalpy
- Reaction Enthalpy
- Hess's Law
- Formation Enthalpy
- Hrxn from Hformation
- Hrxn Temp Dependence
- First Law / Enthalpy Review
- Spontaneous Processes
- Entropy
- Expansion Entropy
- Second Law
- Entropy Example
- Statistical Entropy
- Gibbs Entropy
- Reversible Entropy
- Heat Engines
- Second Law / Entropy Review
- Entropy Temp Dependence 1
- Entropy Temp Dependence 2
- Third Law
- Transition Entropy
- Debye T^3 Law
- Absolute Calorimetric Entropy
- Absolute Statistical Entropy
- Residual Entropy
- Reaction Entropy
- Third Law / Absolute Entropy Review
- Helmholtz Energy
- Gibbs Energy
- Natural Variables
- Maxwell Relations: Concept
- Maxwell Relations: Summary
- Maxwell Relations: Example
- Standard Entropy Correction
- Gibbs-Helmholtz Equation
- Fugacity
- Fugacity Coefficient
- Gibbs / Helmholtz Energy Review
- Phase Diagrams
- Gibbs Energy of Phases
- Chemical Potential
- Clapeyron Equation
- Clausius-Clapeyron Equation
- Statistical Chemical Potential
- Phase Diagrams Review
- Partial Molar Quantities
- Gibbs-Duhem Equation
- Solution Chemical Potential
- Raoult's Law
- Pressure-Composition Diagram
- Temperature-Composition Diagram
- Energy of Mixing
- Henry's Law
- Activity
- Standard Activity
- Liquid-Liquid Solutions Review
- Molality and Molarity
- Non-Volatile Solutes
- Colligative Properties
- Freezing Point Depression
- Osmotic Pressure
- Electrolyte Activity
- Debye-Huckel Law
- Solid-Liquid Solutions Review
- Extent of Reaction
- Equilibrium Constant Derivation
- Le Chatalier's Principle
- Concentration Equilibrium Constant
- Standard Reaction Gibbs Energy
- Equilibrium Gibbs Energy
- Reaction Quotient
- Reaction Spontaneity
- Van't Hoff Equation
- Fugacity Equilibrium Constant
- Activity Equilibrium Constant
- Condensed Phase Activity
- Equilibrium Review
- Electrochemical Cells
- Half Cell Reactions
- Cell Diagrams
- Electromotive Force
- Nernst Equation
- Standard Reduction Potential
- Electrochemistry Example
- Electrochemical Enthalpy and Entropy
- Ionic Gibbs Energy
- Solubility Product
- Batteries
- Electrochemistry Review
- Summary of Thermodynamics Chapters
- Introduction
- Average Kinetic Energy
- Average Velocity
- Maxwell-Boltzmann Distribution
- Mean Free Path
- Total Collision Rate
- Kinetic Theory of Gases Review
- Reaction Rates
- Rate Laws
- First Order Reactions
- Second Order Reactions
- Half Life
- Determining Rate Laws
- Reversible Reactions
- Activation Energy
- Reaction Coordinate
- Reaction Rates Review
- Reaction Mechanisms
- Detailed Balance
- Rate Determining Step
- Steady-State Approximation
- Unimolecular Reactions
- Catalysis
- Michaelis-Menton Mechanism
- Reaction Mechanisms Review
- Summary of Kinetics Chapters
Course Description
This microlecture series from TMP Chem covers the content of an undergraduate course on chemical thermodynamics and kinetics. Topics include gas equations of state, statistical mechanics, the laws of thermodynamics, enthalpy, entropy, Gibbs and Helmholtz energies, phase diagrams, solutions, equilibrium, electrochemistry, kinetic theory of gases, reaction rates, and reaction mechanisms.
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